研究院概况

李辉

在氢气质子交换膜燃料电池的设计、诊断和耐久性研究方面进行了深入的开拓性的研究,掌握了世界领先的燃料电池核心技术,开发出了独特的燃料电池系统的设计,发明了一系列有关燃料电池的测试诊断工具,深入研究了燃料电池性能衰减的机理和提高耐久性的方法,发表了许多有关燃料电池的优秀论文和专著,赢得了燃料电池国际专家的荣誉,曾经多次被同行国际专家邀请为他们的著作撰写章节。



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李辉,现南方科技大学材料科学与工程系讲席教授。自2007年从事燃料电池研究,先后担任多项重要国家研究项目及国际合作项目的技术负责人,包括与美国能源部(US DOE)的合作项目,与德国国家航空研究中心(DRL)的合作项目, 以及和处于世界领先地位的燃料电池公司(Ballard, Hydrogenics, AFCC, MBFC) 的工业合作项目。在氢气质子交换膜燃料电池的设计、诊断和耐久性研究方面进行了深入的开拓性的研究,掌握了世界领先的燃料电池核心技术,开发出了独特的燃料电池系统的设计,发明了一系列有关燃料电池的测试诊断工具,深入研究了燃料电池性能衰减的机理和提高耐久性的方法,发表了许多有关燃料电池的优秀论文和专著,赢得了燃料电池国际专家的荣誉,曾经多次被同行国际专家邀请为他们的著作撰写章节。2009年受德国著名燃料电池专家Jurgen Garche和美国电化学专家Chris Dyer(Journal of Power Sources主编)的邀请为“电化学能源大全”(Encyclopedia of Electrochemical Power Souces)撰写了“质子交换膜燃料污染”一章; 2010年受CRC出版社的邀请,编写了“质子交换膜燃料电池污染及缓解”专   著; 2011年受CRC出版社的邀请,编写了“质子交换膜燃料电池诊断工具”和“质子交换膜燃料电池失效模式分析”两集手册;2014再次受CRC出版社邀请,编写了“质子交换膜电解水制氢”专著。至今,发表有关氢能与燃料电池的优秀论文50余篇,包括在Chem. Review  及 Progress  in Materials Science发表的该领域的重要综述文章。主编相关专著4部,撰写书籍章节共8章,授权国际专利4项。


教育经历

2002-2006,加拿大哥英属哥伦比亚大学博士,电化学工程

1987-1990,清华大学硕士,化学工程

1982-1987,清华大学学士,化学工程

 

工作经历

2015-至今,南方科技大学,讲席教授

2015-至今,南非西北大学,荣誉教授

2013-至今,加拿大英属哥伦比亚大学,兼职教授

 

所获荣誉

深圳市“孔雀计划”A类人才

南科杰出学者

 

研究内容

1.燃料电池关键材料及部件,包括低铂及非铂氧还原催化剂、质子交换膜、双极板及膜电极

2.水电解制氢先进技术研发平台,包括催化剂及膜电极的构效关系与优化、单电池及电堆的性能评价和诊断工具

3.氢气储存技术和材料,包括高压储氢,金属氢化物、多孔材料及有机物等储氢

4.用于能智能电网的电化学储能, 包括金属空气电池,液流电池,二氧化碳电化学还原技术等

 

代表性论文

  1. Yajun Wang, Xiaojun Xie, Chang Zhou, Qi Feng, Yong Zhou, Xiao-Zi Yuan, Jiaoyan Xu, Jiantao Fan, Lin Zeng, Hui Li*, Haijiang Wang*. Study of relative humidity on durability of the reversal tolerant proton exchange membrane fuel cell anode using a segmented cell, Journal of power sources. Journal of Power Sources 449 (2020) 227542 

  2. Yao Yao, Qi Feng, Shangqian Zhu, Jiadong Li, Yuze Yao, Yajun Wang, Qi Wang, Meng Gu, Haijiang Wang*, Hui Li*, Xiao‐Zi Yuan, Minhua Shao*, Chromium Oxynitride Electrocatalysts for Electrochemical Synthesis of Ammonia Under Ambient Conditions,Small Methods 2019,3(6):1800324

  3. Ming Chen*, Chen Zhao, Fengman Sun*, Jiantao Fan, Hui Li, Haijiang Wang*,Research progress of catalyst layer and interlayer interface structures in membrane electrode assembly (MEA) for proton exchange membrane fuel cell (PEMFC) system,eTransportation,Volume 5,100075.

  4. Q. Feng, J. Zou, Y. Wang, Z..g Zhao, M. C. Willams, H. Li *, H. Wang*. Influence of Surface Oxygen Vacancies and Ruthenium Valence State on the Catalysis of Pyrochlore Oxides. ACS Applied Materials and Interfaces,12(4),4520-4530.

  5. Yajun Wang, Xiaoming Zhang, Qi Feng, Jiexin Zou, Chang Zhou, Lin Zeng, Jiantao Fan, Haizhu Zhao, Huaqiang Huang, Huang Fu, Hui Li*, Haijiang Wang*, Investigation of three system shut-down strategies alongside optimization suggestion for proton exchange membrane fuel cells via in-situ measurements, International Journal of Green Energy, 2020,17(2):157-170.

  6. Qi Feng , Zhen Zhang , Henghui Huang , Keguang Yao , Jiantao Fan , Lin Zeng, Mark C. Williams , Hui Li , Haijiang Wang, An effective strategy to tune the oxygen vacancy of pyrochlore oxides for electrochemical energy storage and conversion systems, Chemical Engineering Journal 395 (2020) 124428

  7. Yao Yao, Shangqian Zhu, Haijiang Wang, Hui Li*, Minhua Shao* A Spectroscopic Study of Electrochemical Nitrogen and Nitrate Reduction on Rhodium Surfaces. Angew. Chem. Int. Ed. 2020, 59, 10479-10483.

  8. Y. Yao, J. Wang, U. B. Shahid, M. Gu, H. Wang, H. Li*, M. Shao* Electrochemical Synthesis of Ammonia from Nitrogen under Mild Conditions: Current Status and Challenges. Electrochemical Energy Reviews, 2020, 3, 239–270.

  9. Henghui Huang, Liwen Ni, Jiaoyan Xu, Cheng Yang, Li Zhang, Xiaojun Xie, Jiantao Fan*, Hui Li* and Haijiang Wang. In situ cross-linked vinylphosphonic acid-modified aminosilicon oxide gel electrolyte for proton exchange membrane fuel cells, Sustainable Energy Fuels.2020,4,2859-2868

  10.  Henghui Huang, Jiaoyan Xu, Qi Feng, Liwen Ni, Li Zhang, Cheng Yang, Jiantao Fan*,Hui Li*, Haijiang Wang. Poly-hydroxyethylidene-1,1-diphosphonic acid (PHEDP) as a highly effective water-retentive and proton-conductive material for low-humidity proton exchange membranes, Journal of Membrane Science, 2020,606,118144

  11. Cheng Yang, Ning Han, Wang, Yajun, Yuan, Xiao-Zi, Jiaoyan Xu, Henghui Huang, Jiantao Fan*, Hui  Li*, Haijiang Wang, A Novel Approach to Fabricate Membrane Electrode Assembly by Directly Coating the Nafion Ionomer on Catalyst Layers for Proton-Exchange Membrane Fuel Cells, ACS Sustainable Chemistry & Engineering 8(26) (2020) 9803-9812.

  12. J. Zou, N. Han, J. Yan, Q. Feng, Y. Wang, Z. Zhao, J. Fan, L, Zeng*, H. Li *, H. Wang*. Electrochemically compressing technologies to produce high-pressure hydrogen: Current Status, Challenges and Future Prospects. Electrochemical Energy Reviews (2020). 

  13. Henghui Huang, Shaoyi Xu, Li Zhang, Jiantao Fan*, Hui Li*, Haijiang Wang.A self-humidifying proton exchange membrane embedded with phosphonic acid-functionalized mesoporous silica nanoparticles that has excellent dispersion and water retention.Sustainable Energy Fuels.2020

  14. Zhi Liang Zhao#, Qi Wang#, Xiang Huang#, Qi Feng, Shuang Gu, Zhen Zhang, Hu Xu*, Lin Zeng*, Meng Gu* and Hui Li*  Boosting Oxygen Evolution Reaction Using Defect-rich Ultra-Thin Ruthenium Oxide Nanosheets in Acidic Media, Energy & Environmental Science

  15. Yajun Wang, Chang Zhou, Xiaojun Xie, Cheng Yang, Qi Feng, Jiexin Zou , Xiao-Zi Yuan, Jiantao Fan, Lin Zeng, Hui Li*, Haijiang Wang*, Study of failure mechanisms of the reversal tolerant fuel cell anode via novel in-situ measurements. International Journal of Hydrogen Energy, 2020,45(1):996-1007.

  16. Qi Feng,  Lin Zeng, Jiaoyan Xu, Zhen Zhang, Zhiliang Zhao, Yajun Wang, Hui Li,  Haijiang Wang,NaCl template-directed approach to ultrathin lamellar molybdenum phosphide-carbon hybrids for efficient hydrogen production,Journal of Power Sources 438 (2019) 227048.

  17. Qi Feng, Yongyueheng Xiong, Linjing Xie, Zhen Zhang, Xiner Lu, Yajun Wang, Xiao-Zi Yuan, Jiantao Fan, Hui Li,* and Haijiang Wang*,Tungsten Carbide Encapsulated in Grape-Like N‑Doped Carbon Nanospheres: One-Step Facile Synthesis for Low-Cost and Highly Active Electrocatalysts in Proton Exchange Membrane WaterElectrolyzers,ACS Appl. Mater. Interfaces,2019, 11(28),25123-25132.

  18. Xiao‐Zi Yuan, Chaojie Song, Alison Platt, Nana Zhao, Haijiang Wang ,Hui Li, Khalid Fatih, Darren Jang. A review of all-vanadium redox flow battery durability: Degradation mechanisms and mitigation strategies in International Journal of Energy Research, International Journal of Energy Research

  19. Yao Yao, Haijiang Wang, Xiao-zi Yuan, Hui Li,* and Minhua Shao*,Electrochemical Nitrogen Reduction Reaction on Ruthenium,ACS Energy Lett. 2019, 4, 1336−1341.

  20. Zhen Zhang, Ping Li, Qi Wang, Qi Feng, Youkun Tao, Jiaoyan Xu,Cheng Jiang, Xiner Lu, Jiantao Fan, Meng Gu, Hui Li * and Haijiang Wang*,J. Mater. Chem. A, 2019, 7, 2780

  21.  Lun Wang, Youkun Tao*, Zhen Zhang, Yajun Wang, Qi Feng, Haijiang Wang, and Hui Li*, Molybdenum Carbide Coated 316L Stainless Steel for Bipolar Plates of Proton Exchange Membrane Fuel Cells, International Journal of Hydrogen Energy. 44(2019) 4940-4950

  22. Qi Feng, Qi Wang, Zhen Zhang, Yongyueheng Xiong, Hanyi Li, Yao Yao, Xiao-ZiYuan, Mark C.Williams, Meng Gu, Hong Chen, Hui Li, Haijiang Wang, Highly active and stable ruthenate pyrochlore for enhanced oxygen evolution reaction in acidic medium electrolysis,Applied catalysis b: environmental,  2019, 244, 494-501

  23. Yao Yao, Qi Feng, Shangqian Zhu, Jiadong Li, Yuze Yao, Yajun Wang, Qi Wang, Meng Gu, Haijiang Wang*, Hui Li*, Xiao‐Zi Yuan, Minhua Shao*, “Chromium Oxynitride Electrocatalysts for Electrochemical Synthesis of Ammonia Under Ambient Conditions”,Small Methods 2018, 1800324 https://doi.org/10.1002/smtd.201800324

  24. Zhen Zhang, Ping Li, Qi Feng, Bing Wei, Chenglong Deng, Jiantao Fan, Hui Li,*and Haijiang Wang*,Scalable Synthesis of a Ruthenium-Based Electrocatalyst as a Promising Alternative to Pt for Hydrogen Evolution Reaction,ACS Appl. Mater. Interfaces.2018, 10, 32171−32179

  25. Qi Feng, Xiao−ZiYuan, GaoyangLiu, BingWei, ZhenZhang, HuiLi*, HaijiangWang*.A review of proton exchange membrane water electrolysis on degradation mechanisms and mitigation strategies,Journal of Power Sources. Volume 2017,366(31),33-55.

  26. Yao Yao, Shangqian Zhu, Haijiang Wang, Hui Li, and Minhua Shao* A Spectroscopic Study on the Nitrogen Electrochemical ReductionReaction on Gold and Platinum Surfaces. J. Am. Chem. Soc. 2018, 140, 1496−1501.

  27.   Yan-Jie Wang , Baizeng Fang , Hui Li, Xiaotao T. Bi, Haijiang Wang。 “Progress in modified carbon support materials for Pt and Pt-alloy cathode catalysts in polymer electrolyte membrane fuel cells”,Progress in Materials Science 82(2016)445-498

  28.   Yanjie Wang, Nana. Zhao, Zheng Bai, Hui Li, Tony Bi, Haijinag Wang. “Effect of different solvent ratio (ethylene glycol/water) on the preparation of Pt/C catalyst and its activity toward oxygen reduction reaction ”. RCS Advances.  5 (2015) 56570-56577

  29.    Yanjie Wang, Nana. Zhao, Zheng Bai, Hui Li, Haijinag Wang, Tony Bi. “Carbon-Supported Pt-Based Alloy Electrocatalysts for the Oxygen Reduction Reaction in Polymer Electrolyte Membrane Fuel Cells: Particle Size, Shape, and Composition Manipulation and Their Impact to Activity”. Chemical Reviews, 115(2015) 3433-3467

  30.  Lei Zhang, Hui Li, Jiujun Zhang. “Kinetics of oxygen reduction reaction on three different Pt surfaces of Pt/C catalyst analyzed by rotating ring-disk electrode in acidic solution”. Journal of Power Sources, 255 (2014) 242-250.

  31.   Zhu Chen, Aiping Yu, Drew Higgins, Hui Li, Haijiang Wang, Zhongwei Chen. “Highly active and durable core-corona structured bifunctional catalyst for rechargeable metal-air battery applications”. Nano Letters, 12 (2012) 1946-1652.

  32.   Zhu Chen, Aiping Yu, Raihan Ahmed, Haijiang Wang, Hui Li, Zhongwei Chen. “Manganese Dioxide Nanotube and Nitrogen-doped Carbon Nanotube Based Composite Bifunctional Catalyst for Rechargeable Zinc-Air Battery”. Electrochim. Acta, 69(2012)295-300.

  33.   Yi Yu, Xiao-Zi Yuan, Hui Li, Elton Gu, Haijiang Wang, Guangjin Wang, Mu Pan. “Current mapping of a PEM fuel cell with a segmented current collector during the gas starvation and shutdown process”. Intern. J. Hydrogen Energy 37 (2012) 15288-15300.

  34.   Xiao-Zi Yuan, Hui Li, Yi Yu, Max Jiang, Weimin Qian, Shengsheng Zhang, Haijiang Wang, Silvia Wessel, Tommy Cheng. “Diagnosis of contamination introduced by ammonia at the cathode in a PEM fuel cell”. Intern. J. Hydrogen Energy 37 (2012) 12464-12473.

  35.   Hui Li, Shengsheng Zhang, Weimin Qian, Yi Yu, Xiao-Zi Yuan, Haijiang Wang, Max Jiang, Silvia Wessel, Tommy Cheng. “Impacts of operating conditions on the effects of chloride contamination on PEM fuel cell performance and durability”. J Power Sources. 218 (2012) 375-382.

  36.   Yi Yu, Hui Li, Haijiang Wang, Xiao-Zi Yuan, Guangjin Wang, Mu Pan. “A review on performance degradation of proton exchange membrane fuel cells during startup and shutdown processes: Causes, consequences, and mitigation strategies”. J Power Sources. 205 (2012) 10-23.

  37.   Alfred Lam, Hui Li, Shengsehng Zhang, Haijiang Wang, David Wilkinson, Silvia Wessel, Tommy T. H. Cheng. “Ex situ study of chloride contamination on carbon supported Pt catalyst”. J. Power Sources. 205 (2012) 235-238.

  38.   Xiao-Zi Yuna, Jian Colin Sun, Haijiang Wang, Hui Li. “Accelerated conditioning for a proton exchange membrane fuel cell”. J. Power Sources. 205 (2012) 340-344.

  39.   Shengsheng Zhang, Xiao-Zi Yuna, Renate Hiesgen, K. Andreas Friedrich, Haijiang Wang, Mathias Schulze, Andrea Haug, Hui Li. “ Effect of open voltage on degradation of a short proton change membrane fuel cell stack with bilayer membrane configuration”. J Power Sources. 205 (2012) 290-300.

  40.   Bing Li, Drew C. Higgins, Shaomin Zhu, Hui Li, Haijiang Wang, Jianxin Ma, Zhongwei Chen.“Highly Active Pt-Ru Nanowire Network Catalysts for the Methanol Oxidation Reaction”. Catalysis Communications, 18(2012)51-54.


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